![]() Carbohydrates and Sugars: Finally, Some Reactions! (Advanced) References and Further Readingġ.How To Get Around The Selectivity Problem? A Glimpse Into Org 3.Ethers At C-1 (The Anomeric Carbon) Can Be Cleaved Selectively.A Brute Force Way Around Selectivity: Excess Reagent. ![]() Reactions Of The Alcohol Groups Of Sugars: The Problem Of Selectivity.Hydrolysis of The Glycosidic Bond Of Disaccharides.Formation of Disaccharides (In Theory, If Not In Practice).Hydrolysis of Glycosides with Aqueous Acid.Reactions At The Hemiacetal (Anomeric) Carbon: Formation And Hydrolysis Of “Glycosides”.Carbohydrates and Sugars: Finally, Some Reactions!.How to “deprotect” the anomeric (C-1) carbon selectively.Reactions on the -OH groups of sugars, including protecting groups.Hydrolysis of glycosidic bonds (glycosides), which is exactly like hydrolysis of acetals (aqueous acid).Formation of “ glycosides” – just a different name for acetals when they exist at the “anomeric” carbon of sugars.In this post we introduce some simple reactions of sugars, especially glycosylation and protection: ![]() Finally, Some Reactions Of Sugars: Glycosylation And Protection ![]()
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